 
data_thunderbayite
 
_audit_creation_method            SHELXL-97
_chemical_name_systematic
;
 ?
;
_chemical_name_common             'thunderbayite'
_chemical_melting_point           ?
_chemical_formula_moiety          ?
_chemical_formula_sum
 'Ag3 Au3 S6 Sb7 Tl'
_chemical_formula_weight          2163.49
 
loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'Ag'  'Ag'  -0.8971   1.1015
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Au'  'Au'  -2.0133   8.8022
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'S'  'S'   0.1246   0.1234
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Tl'  'Tl'  -2.8358   9.6688
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Sb'  'Sb'  -0.5866   1.5461
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
_symmetry_cell_setting            'triclinic'
_symmetry_space_group_name_H-M    'P1'
 
loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 
_cell_length_a                    8.088(3)
_cell_length_b                    7.854(3)
_cell_length_c                    20.078(8)
_cell_angle_alpha                 92.52(3)
_cell_angle_beta                  93.71(3)
_cell_angle_gamma                 90.15(4)
_cell_volume                      1271.5(8)
_cell_formula_units_Z             2
_cell_measurement_temperature     295(2)
_cell_measurement_reflns_used     4256
_cell_measurement_theta_min       5.85
_cell_measurement_theta_max       13.26
 
_exptl_crystal_description        block
_exptl_crystal_colour             black
_exptl_crystal_size_max           0.050
_exptl_crystal_size_mid           0.035
_exptl_crystal_size_min           0.025
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     5.651
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              1824
_exptl_absorpt_coefficient_mu     33.569
_exptl_absorpt_correction_type    'multi-scan'
_exptl_absorpt_correction_T_min   0.245
_exptl_absorpt_correction_T_max   0.461
_exptl_absorpt_process_details    
'(ABSPACK; Bruker Inc., 2016)'
 
_exptl_special_details
;
 ?
;
 
_diffrn_ambient_temperature       295(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device_type   'Bruker D8 Venture'
_diffrn_measurement_method        'ω scans'
_diffrn_detector_area_resol_mean  ?
_diffrn_standards_number          ?
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   .
_diffrn_standards_decay_%         .
_diffrn_reflns_number             18799
_diffrn_reflns_av_R_equivalents   0.0208
_diffrn_reflns_av_sigmaI/netI     0.0145
_diffrn_reflns_limit_h_min        -7
_diffrn_reflns_limit_h_max        9
_diffrn_reflns_limit_k_min        -9
_diffrn_reflns_limit_k_max        9
_diffrn_reflns_limit_l_min        -30
_diffrn_reflns_limit_l_max        30
_diffrn_reflns_theta_min          3.05
_diffrn_reflns_theta_max          33.74
_reflns_number_total              6799
_reflns_number_gt                 5521
_reflns_threshold_expression      >2sigma(I)
 
_computing_data_collection        'APEX3 (Bruker Inc., 2016)'
_computing_cell_refinement        'APEX3 (Bruker Inc., 2016)'
_computing_data_reduction         'APEX3 (Bruker Inc., 2016)'
_computing_structure_solution     'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics     'DIAMOND (Brandenburg, 2001)'
_computing_publication_material   'SHELXL-97 (Sheldrick, 2008)'
 
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
 
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[σ²(Fo²)+(0.0365P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    .
_refine_ls_hydrogen_treatment     .
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_abs_structure_details
 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack    0.008(3)
_refine_ls_number_reflns          6799
_refine_ls_number_parameters      361
_refine_ls_number_restraints      3
_refine_ls_R_factor_all           0.0245
_refine_ls_R_factor_gt            0.0220
_refine_ls_wR_factor_ref          0.0635
_refine_ls_wR_factor_gt           0.0631
_refine_ls_goodness_of_fit_ref    1.058
_refine_ls_restrained_S_all       1.058
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000
 
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Tl1 Tl 0.51983(10) 0.01613(9) 0.98984(4) 0.0874(2) Uani 1 1 d . . .
Tl2 Tl 0.48208(9) 0.51764(9) 0.04759(3) 0.07683(19) Uani 1 1 d . . .
Ag1 Ag -0.01841(13) -0.01304(12) 0.23420(5) 0.0506(2) Uani 1 1 d . . .
Ag2 Ag -0.01990(12) -0.01104(11) 0.52154(4) 0.0431(2) Uani 1 1 d . . .
Ag3 Ag -0.0225(2) -0.0150(2) 0.81150(8) 0.0932(4) Uani 1 1 d . . .
Ag4 Ag 0.47704(16) 0.51585(16) 0.33949(6) 0.0694(3) Uani 1 1 d . . .
Ag5 Ag 0.48161(13) 0.52001(13) 0.60460(5) 0.0520(2) Uani 1 1 d . . .
Ag6 Ag 0.4800(2) 0.5239(2) 0.90808(7) 0.0919(4) Uani 1 1 d . . .
Au1 Au 0.51393(9) 0.01835(9) 0.13515(4) 0.07904(19) Uani 1 1 d . . .
Au2 Au 0.51381(8) 0.02540(8) 0.42869(3) 0.06754(17) Uani 1 1 d . . .
Au3 Au 0.51237(6) 0.02224(6) 0.69923(2) 0.04881(13) Uani 1 1 d . . .
Au4 Au 0.01811(7) 0.48143(7) 0.14738(3) 0.05465(15) Uani 1 1 d . . .
Au5 Au 0.01606(8) 0.48648(8) 0.44131(3) 0.06506(17) Uani 1 1 d . . .
Au6 Au 0.01594(9) 0.48543(9) 0.70939(3) 0.07471(19) Uani 1 1 d . . .
Sb1 Sb 0.62225(13) 0.62812(13) 0.17843(5) 0.0636(3) Uani 1 1 d . . .
Sb2 Sb 0.62487(18) 0.63013(18) 0.46532(7) 0.0897(4) Uani 1 1 d . . .
Sb3 Sb 0.62270(15) 0.62770(15) 0.75223(6) 0.0754(3) Uani 1 1 d . . .
Sb4 Sb 0.87755(14) 0.35372(13) 0.00921(5) 0.0624(2) Uani 1 1 d . . .
Sb5 Sb 0.87418(13) 0.37729(12) 0.32541(5) 0.0588(2) Uani 1 1 d . . .
Sb6 Sb 0.87037(16) 0.37047(16) 0.58138(6) 0.0825(4) Uani 1 1 d . . .
Sb7 Sb 0.87271(12) 0.37430(12) 0.87835(4) 0.0551(2) Uani 1 1 d . . .
Sb8 Sb 0.12319(17) 0.87655(17) 0.10718(6) 0.0860(3) Uani 1 1 d . . .
Sb9 Sb 0.12482(14) 0.87839(14) 0.39822(5) 0.0717(3) Uani 1 1 d . . .
Sb10 Sb 0.12395(13) 0.87710(13) 0.66835(5) 0.0611(2) Uani 1 1 d . . .
Sb11 Sb 0.12450(11) 0.87638(11) 0.95727(4) 0.0503(2) Uani 1 1 d . . .
Sb12 Sb 0.37074(14) 0.12834(14) 0.24922(5) 0.0695(3) Uani 1 1 d . . .
Sb13 Sb 0.37429(12) 0.12933(12) 0.53772(4) 0.0533(2) Uani 1 1 d . . .
Sb14 Sb 0.37250(19) 0.12923(19) 0.82125(7) 0.0972(4) Uani 1 1 d . . .
S1 S 0.3705(7) 0.3825(6) 0.1687(2) 0.0900(13) Uani 1 1 d . . .
S2 S 0.3752(5) 0.3884(4) 0.45807(16) 0.0568(8) Uani 1 1 d . . .
S3 S 0.3827(4) 0.3870(4) 0.71542(14) 0.0464(7) Uani 1 1 d . . .
S4 S 0.1269(6) 0.6182(5) 0.2757(2) 0.0730(11) Uani 1 1 d . . .
S5 S 0.1230(7) 0.6249(7) 0.5723(2) 0.0872(13) Uani 1 1 d . . .
S6 S 0.1251(4) 0.6231(4) 0.84379(14) 0.0474(7) Uani 1 1 d . . .
S7 S 0.8750(3) 0.1206(3) 0.11298(12) 0.0361(6) Uani 1 1 d . . .
S8 S 0.8792(7) 0.1167(7) 0.3989(3) 0.0933(14) Uani 1 1 d . . .
S9 S 0.8795(5) 0.1237(5) 0.69460(19) 0.0703(10) Uani 1 1 d . . .
S10 S 0.6162(6) 0.8830(6) 0.3086(2) 0.0753(11) Uani 1 1 d . . .
S11 S 0.6170(5) 0.8860(5) 0.57502(17) 0.0625(9) Uani 1 1 d . . .
S12 S 0.6227(5) 0.8803(4) 0.85802(16) 0.0550(8) Uani 1 1 d . . .
 
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
 
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Tl1 Au1 2.9203(15) 1_556 ?
Tl1 S12 2.980(3) 1_545 ?
Tl1 Sb11 3.3917(18) 1_545 ?
Tl2 Ag6 2.803(2) 1_554 ?
Tl2 Sb1 2.8893(17) . ?
Tl2 S1 2.891(5) . ?
Ag1 S7 2.780(3) 1_455 ?
Ag1 Sb8 2.9590(19) 1_545 ?
Ag1 Sb12 3.326(2) . ?
Ag2 S8 2.774(5) 1_455 ?
Ag2 Sb9 2.9063(17) 1_545 ?
Ag2 Sb10 3.2563(19) 1_545 ?
Ag2 Sb6 3.323(2) 1_455 ?
Ag3 S9 2.704(5) 1_455 ?
Ag3 Sb11 3.238(2) 1_545 ?
Ag3 Sb10 3.258(2) 1_545 ?
Ag4 S2 2.794(4) . ?
Ag4 Sb2 2.832(2) . ?
Ag5 S3 2.667(3) . ?
Ag5 Sb3 3.1843(19) . ?
Ag5 Sb2 3.246(2) . ?
Ag6 Tl2 2.8026(19) 1_556 ?
Au1 Sb12 2.7399(16) . ?
Au1 Tl1 2.9203(15) 1_554 ?
Au1 Sb1 3.3265(19) 1_545 ?
Au2 Sb13 2.6267(14) . ?
Au2 S10 2.789(4) 1_545 ?
Au2 Sb2 3.334(2) 1_545 ?
Au3 S11 2.850(4) 1_545 ?
Au3 Sb14 2.8584(18) . ?
Au3 Sb10 3.3497(18) 1_545 ?
Au4 S4 2.833(4) . ?
Au4 S1 2.965(6) . ?
Au4 Sb4 3.0556(17) 1_455 ?
Au5 Sb5 2.6346(16) 1_455 ?
Au5 S5 2.880(5) . ?
Au5 Sb6 3.2827(18) 1_455 ?
Au6 Sb6 2.8646(18) 1_455 ?
Au6 S6 2.943(3) . ?
Au6 Sb10 3.3477(18) . ?
Sb1 S1 2.793(5) . ?
Sb1 Au1 3.3265(19) 1_565 ?
Sb2 S2 2.761(4) . ?
Sb2 S11 2.919(4) . ?
Sb2 Au2 3.334(2) 1_565 ?
Sb3 S3 2.750(3) . ?
Sb3 S12 2.842(3) . ?
Sb4 Sb7 2.6372(17) 1_554 ?
Sb4 S7 2.835(3) . ?
Sb4 Au4 3.0556(17) 1_655 ?
Sb5 S8 2.575(6) . ?
Sb5 Au5 2.6346(16) 1_655 ?
Sb6 Au6 2.8646(18) 1_655 ?
Sb6 S5 2.874(5) 1_655 ?
Sb6 Au5 3.2827(18) 1_655 ?
Sb6 Ag2 3.323(2) 1_655 ?
Sb7 Sb4 2.6372(17) 1_556 ?
Sb8 S7 2.784(3) 1_465 ?
Sb8 Ag1 2.9590(19) 1_565 ?
Sb8 Sb11 3.0107(19) 1_554 ?
Sb9 S8 2.733(6) 1_465 ?
Sb9 Ag2 2.9063(17) 1_565 ?
Sb10 S5 2.702(5) . ?
Sb10 S9 2.829(5) 1_465 ?
Sb10 Ag2 3.2563(19) 1_565 ?
Sb10 Ag3 3.258(2) 1_565 ?
Sb10 Au3 3.3497(18) 1_565 ?
Sb11 Sb8 3.0107(18) 1_556 ?
Sb11 Ag3 3.238(2) 1_565 ?
Sb11 Tl1 3.3917(18) 1_565 ?
Sb12 S1 2.624(5) . ?
Sb13 S2 2.643(4) . ?
Sb13 S11 2.832(4) 1_545 ?
Sb14 S12 2.901(4) 1_545 ?
S5 Sb6 2.874(5) 1_455 ?
S7 Ag1 2.780(3) 1_655 ?
S7 Sb8 2.784(3) 1_645 ?
S8 Sb9 2.733(6) 1_645 ?
S8 Ag2 2.774(5) 1_655 ?
S9 Ag3 2.704(5) 1_655 ?
S9 Sb10 2.829(5) 1_645 ?
S10 Au2 2.789(4) 1_565 ?
S11 Sb13 2.832(4) 1_565 ?
S11 Au3 2.850(4) 1_565 ?
S12 Sb14 2.901(4) 1_565 ?
S12 Tl1 2.980(3) 1_565 ?
 
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
Au1 Tl1 S12 153.80(8) 1_556 1_545 ?
Au1 Tl1 Sb11 95.98(4) 1_556 1_545 ?
S12 Tl1 Sb11 92.47(8) 1_545 1_545 ?
Ag6 Tl2 Sb1 150.18(5) 1_554 . ?
Ag6 Tl2 S1 151.84(11) 1_554 . ?
Sb1 Tl2 S1 57.79(10) . . ?
S7 Ag1 Sb8 57.94(7) 1_455 1_545 ?
S7 Ag1 Sb12 100.42(7) 1_455 . ?
Sb8 Ag1 Sb12 75.23(5) 1_545 . ?
S8 Ag2 Sb9 57.48(12) 1_455 1_545 ?
S8 Ag2 Sb10 173.61(11) 1_455 1_545 ?
Sb9 Ag2 Sb10 123.25(5) 1_545 1_545 ?
S8 Ag2 Sb6 83.93(12) 1_455 1_455 ?
Sb9 Ag2 Sb6 132.20(5) 1_545 1_455 ?
Sb10 Ag2 Sb6 92.11(5) 1_545 1_455 ?
S9 Ag3 Sb11 170.88(11) 1_455 1_545 ?
S9 Ag3 Sb10 55.72(10) 1_455 1_545 ?
Sb11 Ag3 Sb10 126.51(7) 1_545 1_545 ?
S2 Ag4 Sb2 58.77(8) . . ?
S3 Ag5 Sb3 55.21(7) . . ?
S3 Ag5 Sb2 171.96(9) . . ?
Sb3 Ag5 Sb2 127.31(5) . . ?
Sb12 Au1 Tl1 149.09(5) . 1_554 ?
Sb12 Au1 Sb1 99.30(5) . 1_545 ?
Tl1 Au1 Sb1 105.95(4) 1_554 1_545 ?
Sb13 Au2 S10 170.77(9) . 1_545 ?
Sb13 Au2 Sb2 101.53(5) . 1_545 ?
S10 Au2 Sb2 75.93(10) 1_545 1_545 ?
S11 Au3 Sb14 172.67(8) 1_545 . ?
S11 Au3 Sb10 93.15(8) 1_545 1_545 ?
Sb14 Au3 Sb10 79.90(5) . 1_545 ?
S4 Au4 S1 73.85(14) . . ?
S4 Au4 Sb4 175.42(10) . 1_455 ?
S1 Au4 Sb4 110.50(10) . 1_455 ?
Sb5 Au5 S5 171.43(11) 1_455 . ?
Sb5 Au5 Sb6 120.36(5) 1_455 1_455 ?
S5 Au5 Sb6 55.13(11) . 1_455 ?
Sb6 Au6 S6 172.83(8) 1_455 . ?
Sb6 Au6 Sb10 97.66(5) 1_455 . ?
S6 Au6 Sb10 81.64(7) . . ?
S1 Sb1 Tl2 61.13(11) . . ?
S1 Sb1 Au1 116.32(12) . 1_565 ?
Tl2 Sb1 Au1 85.64(5) . 1_565 ?
S2 Sb2 Ag4 59.93(8) . . ?
S2 Sb2 S11 115.84(11) . . ?
Ag4 Sb2 S11 145.51(10) . . ?
S2 Sb2 Ag5 62.44(8) . . ?
Ag4 Sb2 Ag5 121.97(6) . . ?
S11 Sb2 Ag5 61.55(8) . . ?
S2 Sb2 Au2 116.50(10) . 1_565 ?
Ag4 Sb2 Au2 88.39(6) . 1_565 ?
S11 Sb2 Au2 62.00(9) . 1_565 ?
Ag5 Sb2 Au2 111.67(5) . 1_565 ?
S3 Sb3 S12 127.92(10) . . ?
S3 Sb3 Ag5 52.80(7) . . ?
S12 Sb3 Ag5 145.67(9) . . ?
Sb7 Sb4 S7 143.31(7) 1_554 . ?
Sb7 Sb4 Au4 148.56(5) 1_554 1_655 ?
S7 Sb4 Au4 63.18(6) . 1_655 ?
S8 Sb5 Au5 74.87(12) . 1_655 ?
Au6 Sb6 S5 67.23(11) 1_655 1_655 ?
Au6 Sb6 Au5 122.10(5) 1_655 1_655 ?
S5 Sb6 Au5 55.31(10) 1_655 1_655 ?
Au6 Sb6 Ag2 117.60(6) 1_655 1_655 ?
S5 Sb6 Ag2 112.75(11) 1_655 1_655 ?
Au5 Sb6 Ag2 81.39(4) 1_655 1_655 ?
S7 Sb8 Ag1 57.80(6) 1_465 1_565 ?
S7 Sb8 Sb11 93.50(7) 1_465 1_554 ?
Ag1 Sb8 Sb11 151.10(6) 1_565 1_554 ?
S8 Sb9 Ag2 58.82(11) 1_465 1_565 ?
S5 Sb10 S9 129.70(15) . 1_465 ?
S5 Sb10 Ag2 65.72(12) . 1_565 ?
S9 Sb10 Ag2 75.21(9) 1_465 1_565 ?
S5 Sb10 Ag3 143.12(12) . 1_565 ?
S9 Sb10 Ag3 52.16(9) 1_465 1_565 ?
Ag2 Sb10 Ag3 126.79(6) 1_565 1_565 ?
S5 Sb10 Au6 62.28(11) . . ?
S9 Sb10 Au6 112.80(9) 1_465 . ?
Ag2 Sb10 Au6 115.29(5) 1_565 . ?
Ag3 Sb10 Au6 82.78(5) 1_565 . ?
S5 Sb10 Au3 108.81(12) . 1_565 ?
S9 Sb10 Au3 113.60(9) 1_465 1_565 ?
Ag2 Sb10 Au3 109.91(4) 1_565 1_565 ?
Ag3 Sb10 Au3 98.86(5) 1_565 1_565 ?
Au6 Sb10 Au3 121.16(5) . 1_565 ?
Sb8 Sb11 Ag3 152.92(5) 1_556 1_565 ?
Sb8 Sb11 Tl1 83.43(5) 1_556 1_565 ?
Ag3 Sb11 Tl1 111.42(5) 1_565 1_565 ?
S1 Sb12 Au1 71.91(12) . . ?
S1 Sb12 Ag1 103.84(13) . . ?
Au1 Sb12 Ag1 106.36(5) . . ?
Au2 Sb13 S2 72.41(8) . . ?
Au2 Sb13 S11 72.70(8) . 1_545 ?
S2 Sb13 S11 132.76(11) . 1_545 ?
Au3 Sb14 S12 74.49(8) . 1_545 ?
Sb12 S1 Sb1 121.7(2) . . ?
Sb12 S1 Tl2 147.9(2) . . ?
Sb1 S1 Tl2 61.07(11) . . ?
Sb12 S1 Au4 105.34(17) . . ?
Sb1 S1 Au4 120.92(19) . . ?
Tl2 S1 Au4 96.86(16) . . ?
Sb13 S2 Sb2 122.89(15) . . ?
Sb13 S2 Ag4 147.31(14) . . ?
Sb2 S2 Ag4 61.30(8) . . ?
Ag5 S3 Sb3 71.99(9) . . ?
Sb10 S5 Sb6 114.36(17) . 1_455 ?
Sb10 S5 Au5 150.8(2) . . ?
Sb6 S5 Au5 69.56(12) 1_455 . ?
Ag1 S7 Sb8 64.26(8) 1_655 1_645 ?
Ag1 S7 Sb4 155.29(11) 1_655 . ?
Sb8 S7 Sb4 113.37(9) 1_645 . ?
Sb5 S8 Sb9 123.0(2) . 1_645 ?
Sb5 S8 Ag2 146.1(2) . 1_655 ?
Sb9 S8 Ag2 63.70(13) 1_645 1_655 ?
Ag3 S9 Sb10 72.12(12) 1_655 1_645 ?
Sb13 S11 Au3 76.02(10) 1_565 1_565 ?
Sb13 S11 Sb2 107.49(13) 1_565 . ?
Au3 S11 Sb2 154.48(15) 1_565 . ?
Sb3 S12 Sb14 107.51(12) . 1_565 ?
Sb3 S12 Tl1 152.74(13) . 1_565 ?
Sb14 S12 Tl1 77.03(10) 1_565 1_565 ?
 
_diffrn_measured_fraction_theta_max    0.992
_diffrn_reflns_theta_full              33.74
_diffrn_measured_fraction_theta_full   0.992
_refine_diff_density_max    0.562
_refine_diff_density_min   -0.464
_refine_diff_density_rms    0.098
